Modern microprocessor built from complementary carbon nanotube transistors (2024)

Data availability

The data that supports the findings of this study are shown in Figs. 16, Extended Data Figs. 19, and Extended Data Table 1, and are available from the corresponding author on reasonable request.

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Acknowledgements

We acknowledge Analog Devices, Inc. (ADI), the Defence Advanced Research Projects Agency (DARPA) Three-Dimensional System-on-Chip (3DSoC)program, the National Science Foundation and the Air Force Research Laboratory for support. We thank S. Feindt, A. Olney, T. O’Dwyer, S. Gupta and S. Knepper (all at ADI), and Dimitri Antoniadis and Utsav Banerjee (both at MIT) for collaborations.

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Author notes

  1. These authors contributed equally: Gage Hills, Christian Lau

Authors and Affiliations

  1. Department of Electrical Engineering and Computer Science, Massachusetts Institute of Technology (MIT), Cambridge, MA, USA

    Gage Hills,Christian Lau,Andrew Wright,Mindy D. Bishop,Tathagata Srimani,Pritpal Kanhaiya,Rebecca Ho,Aya Amer, Arvind,Anantha Chandrakasan&Max M. Shulaker

  2. Analog Devices, Inc. (ADI), Wilmington, MA, USA

    Samuel Fuller,Yosi Stein&Denis Murphy

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Contributions

G.H. performed all VLSI design aspects of this project (developing and analysing DREAM, creating the CNFET process design kit and designing all standard cells in the CNFET library; he performed the entire RV16X-NANO RTL-to-GDS physical design and led experimental calibration and testing). C.L. performed all fabrication aspects of this project (developing and experimentally demonstrating RINSE, developing, experimentally demonstrating and characterizing MIXED; he developed the fabrication process, and fabricated all ofthe RV16X-NANO wafers and their subsequent packaging to chips). A.W. led the architectural definition of RV16X-NANO (including Bluespec, the Verilog hardware description language and the instruction-set architecture; he also wrote the test programs). S.F. contributed to the architectural definition, system design and implementation. M.D.B., T.S., P.K. and R.H. contributed to developing the fabrication process and establishing the CNFET fabrication flow. A.A. contributed to circuit design. Y.S. and D.M. contributed to project development. A., A.C. and M.M.S. were in charge, advised, and led on all aspects of the project.

Corresponding author

Correspondence to Max M. Shulaker.

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A.C. is a board member at Analog Devices, Inc., and this work was sponsored in part by Analog Devices, Inc.

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Extended data figures and tables

Extended Data Fig. 1 Fabrication process flow for RV16X-NANO.

The fabrication process is a 5-metal-layer (M1 to M5) process and involves >100 individual process steps. s-CNT, semiconducting CNT; S/D, source/drain.

Extended Data Fig. 2 Microscopy image of a full fabricated RV16X-NANO die.

The processor core is in the middle of the die, with test circuitry surrounding the perimeter (when the RV16X-NANO is diced for packaging, these test structures are removed). The test structures include test structures for monitoring fabrication, as well as for measuring and characterizing all of the 63 standard cells in our standard cell library.

Extended Data Fig. 3 CNFET standard cell library.

List of all of the standard cells comprising our standard cell library, along with a microscopy image of each fabricated standard cell, the schematic of each cell, and a typical measured waveform from each fabricated cell. As expected for static CMOS logic stages, the CNFET logic stages exhibit output voltage swing exceeding 99% of VDD, and achieve gain of >15. Experimental waveforms are not shown for cells whose functionality is not demonstrated by output voltage as a function of either input voltage or time; for example, for cells without outputs (for example, fill cells: cell names that start with ‘fill_’ or decap cells:cell names that start with ‘decap_’), for cells whose output is constant (tied high/low: cell names that start with ‘tie_’), or for transmission gates (cell names that start with ‘tg_’).

Extended Data Fig. 4 Image of a completed RV16X-NANO 150-mm wafer.

Each wafer includes 32 dies (single die shown in Extended Data Fig. 2).

Extended Data Fig. 5 Negligible effect of RINSE on CNTs and CNFETs.

a, CNT density is the same pre- versus post-RINSE. b, CNFET IDVGS exhibit minimal change for sets of CNFETs fabricated with and without RINSE (VDS = −1.8 V for all measurements shown). Both samples came from the same wafer, which was diced after the CNT deposition but before the RINSE process. One sample underwent RINSE while the other sample did not. c, CNFETs can still be doped NMOS after the RINSE process, leveraging our MIXED process (VDS = −1.2 V for all measurements shown).

Extended Data Fig. 6 MIXED CNFET CMOS characterization.

a, Definitions ofkey metrics for characterizing logic gates, including SNM, gain and swing. VOH, VIH, VIL and VIL (labelled on the VTCsin a, where (VIL, VOH) and (VIH, VOL) are the points on the VTC whereΔVOUTVIN = −1) are used to extract the noise margin: SNM=min(SNMH, SNML). b, Key metrics extracted for the 10,400 CNFET CMOS nor2 logic gates measured in Fig. 5 (metrics defined in a). This is the largest CNT CMOS demonstration to date, to our knowledge. VDD is 1.2V. c, SNM is extracted based on the distributions from b. We analyse >100 million logic gate pairs based on these experimental results. d, Spatial dependence of VIH (as an example parameter to compute SNM). Each pixel represents the VIH of the nor2 at that location in the die. Importantly, VIH increases across the die (from top to bottom). The change in VIH corresponds with slight changes in CNFET threshold voltage. The fact that the threshold voltage variations are not independently and identically distributed (i.i.d.), but rather have spatial dependence, illustrates that a portion of the threshold voltage variations (and therefore variation in SNM) is due to wafer-level processing-related variations (CNT deposition is more uniform across the 150-mm wafer). Future work should optimize processing steps, for example, increasing the uniformity of the atomic-layer-deposition oxide deposition used for electrostatic doping to further improve SNM for realizing VLSI circuits. e, Wafer-scale CNFET CMOS characterization. Measurements from 4 dies across 150-mm wafer (1,000 CNFET CMOS nor2 logic gates are sampled randomly from the 10,400 such logic gates in each die). No outliers are excluded. Yield and performance variations are negligible across thewafer, illustrated by the distribution of the output voltage swing.

Extended Data Fig. 7 Effect of metallic CNTs on digital VLSI circuits.

a, Reduction in CNFET EDP benefits versus pS (metallic CNTs increase IOFF, degrading EDP). pS ≈ 99.999%, sufficient to minimize EDP cost due to metallic CNTs to ≤5%. b, pNMS versus pS (metallic CNTs degrade SNM), (shown for SNMR=VDD/5, and for a circuit of one million logic gates). Although 99.999% pS is sufficient to limit EDP degradation to ≤5%, panel b shows that SNM imposes far stricter requirements on purity: pS ≈ 99.999999% (that is, number of 9s is 8) to achieve pNMS≥99% (number of 9s is 2). Results in panels a and b are simulated for VLSI circuit modules from a 7-nm node processor core (seeSupplementary Information and Methods for additional details).

Extended Data Fig. 8 Methodology to solve VTCs using CNFET I–V measurements.

a, Experimentally measured ID versus VGS for all 1,000 NMOS (VDS=1.8 V) and 1,000 PMOS CNFETs (VDS=−1.8V), with no CNFETs omitted. Metallic CNTs (m-CNTs) present in some CNFETs result in high off-state leakage current (IOFF=ID at VGS=0V). b, VTC and SNM parameter definitions, for example, for (nand2, nor2). DR is the driving logic stage; LD is the loading logic stage. SNM=min(SNMH, SNML), where SNMH=VOH(DR)VIH(LD) and SNML=VIL(LD)VOL(DR). ce, Methodology to solve VTCs (for example, for nand2) using experimentally measured CNFET IV curves. c, Example ID versus VDS for NMOS and PMOS CNFETs (VGS is swept from −1.8 V to 1.8 V in 0.1-V increments). d, Schematic. To solve a VTC (for example, VOUT versus VA with VB=VDD): for each VA, find V1 and VOUT such that iPA + iPB=iNA=iNB (DC, direct current, convergence). e, Current in the pull-up network (iPU, where iPU=iPA + iPB, and iPA and iPB are the labelled drain currents of the PMOS FETs gated by A and B, respectively) and current in thepull-down network (iPD, where iPD=iNA=iNB, and iNA and iNB are the labelled drain currents of the NMOS FETs gated by A and B, respectively) versus VOUT and VA. The VTC is seen where these currents intersect. CNFETs are fabricated at a ~1 µm technology node, and theCNFET width is 19 µmin panela.

Extended Data Fig. 9 DREAM implementation and methodology.

a, Standard cell layouts (derived using the ‘asap7sc7p5t’standard cell library37), illustrating the importance of CNT correlation: because the length of CNTs (which can be ofthe order of hundreds of micrometres) is typically much longer compared withthe CNFET contacted gate pitch (CGP, for example about42–54 nm for a 7-nm node37), the number of s-CNTs and m-CNTs in CNFETs can be uncorrelated or highly correlated depending on the relative physical placement of CNFET active regions38. For many CMOS standard cell libraries at sub-10-nm nodes (for example refs37,39), the active regions of FETs are highly aligned, resulting in highly correlated number of m-CNTs among CNFETs in library cells, further degrading VTCs (becauseone m-CNT can affect multiple CNFETs simultaneously). bf, Generating a variation-aware CNFET SNM model, shown for a D-flip-flop (dff) derived from the asap7sc7p5t standard cell library37. b, Layout used to extract netlists for each logic stage. c, Schematic: CNFETs are grouped by logic stage (with nodes arbitrarily labelled ‘D’, ‘MH’, ‘MS’, ‘SH’, ‘SS’, ‘CLK’, ‘clkn’, ‘clkb’and ‘QN’ for ease of reference). d, For each extracted netlist, there can be multiple VTCs: for each logic stage output, a logic stage input is sensitized if the output state (0 or 1) depends on the state of that input (given the states of all the other inputs). For example, for a logic stage with Boolean function: Y = !(A*B+C), C is sensitized when (A, B) = (0, 0), (0, 1)or (1, 0). We simulate all possible VTCs (over all logic stage outputs and sensitized inputs), and also in the presence of m-CNTs. For example, panel dshows a subset of the VTCs for the logic stage in panel bwith output node ‘MH’(labelled in panelc), and sensitized input ‘D’(with labelled nodes (‘clkb’, ‘clkn’, ‘MS’) = (0, 1, 0)). The dashed line indicates VTC with no m-CNTs, and the solid lines are example VTCs in the presence of m-CNTs (including the effect of CNT correlation). In each case, we model VOH, VIH, VILand VOL as affine functions of the number of m-CNTs (Mi) in each of r regions (M1, ..., Mr), with calibration parameters in the static noise margin (SNM) model matrix T (shown in panel f). e,Example calibration of the SNM model matrix T for the VTC parameters extracted in panel d; thesymbols are VTC parameters extracted from circuit simulations (using Cadence Spectre),andsolid lines are the calibrated model. f,Affine model form. gj, VLSI design and analysis methodology. g, Industry-practice physical design flow to optimize energy and delay of CNFET digital VLSI circuits, including: (1) library power/timing characterization (using Cadence Liberate) across multiple VDDand using parasitics extracted from standard cell layouts (derived from the asap7sc7p5t standard cell library), in conjunction with a CNFET compact model8. (2) Synthesis (using Cadence Genus), place-and-route (using Cadence Innovus) with back-end-of-line (BEOL) wire parasitics from the ASAP7 process design kit (PDK). (3) Circuit EDP optimization: we sweep both VDD and target clock frequency (during synthesis/place-and-route) to create multiple physical designs. The one with best EDP is used to compare design options (for example, DREAM versus baseline). h, Subset of logic gates in an example circuit module, showing the effect of CNT correlation at the circuit level (for example, the m-CNT counts of CNFETs P3,1 and P5,1 are both equal to M1 + M2 + M3)40. i, Distribution of SNM over all connected logic stage pairs, for a single sample of the circuit m-CNT counts. The minimum SNM for each trial limits the probability that all noise margin constraints in the circuit are satisfied (pNMS). j,Cumulative distribution of minimum SNM over 10,000 Monte Carlo trials, shown for multiple target pS values, where pS is the probability that a given CNT is a semiconducting CNT. These results are used to find pNMSversuspS for a target SNM requirement (SNMR), where pNMS is the fraction of trials that meet the SNM requirement for all logic stage pairs. We note that pNMS can then be exponentiated to adjust for various circuit sizes based on the number of logic gates. k, CNFET compact model parameters (forexample, 7-nm node).

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Modern microprocessor built from complementary carbon nanotube transistors (1)

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Hills, G., Lau, C., Wright, A. et al. Modern microprocessor built from complementary carbon nanotube transistors. Nature 572, 595–602 (2019). https://doi.org/10.1038/s41586-019-1493-8

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Modern microprocessor built from complementary carbon nanotube transistors (2024)

FAQs

What is a carbon nanotube transistor? ›

Carbon nanotube transistors are primed to overtake silicon-based transistors in the near future due to their ideal electrical and thermal properties. CNT transistors will be smaller, run at a much higher frequency, consume less energy, and can even made into free form factors.

Can carbon nanotubes be used for computer components? ›

Carbon nanotube computers are a class of experimental computing processors constructed from carbon nanotube field-effect transistors, instead of from conventional silicon-based field-effect transistors.

What advantage would a carbon nanotube chip have over a silicon chip? ›

Carbon nanotubes, though, are almost as thin as an atom. And they ferry electricity well. As a result, they make better semiconductors than silicon. In principle, carbon nanotube processors could run three times faster than silicon ones.

What is made with the carbon nanotube technology? ›

Carbon nanotubes are currently used in multiple industrial and consumer applications. These include battery components, polymer composites, to improve the mechanical, thermal and electrical properties of the bulk product, and as a highly absorptive black paint.

Can carbon nanotubes be used in electronics? ›

CNTs are considered a viable replacement for ITO transparent conductors in some applications. Fabricated as transparent conductive films (TCF), carbon nanotubes can potentially be used as a highly conductive, transparent and cost efficient alternative in flexible displays and touch screens, for instance.

What is the purpose of carbon nanotubes? ›

CNTs can be used in nanotechnology, automotive parts, electrical circuitry, supercapacitors, photovoltaic technology - including solar panels, LEDs, sensors, transistors, field emitting devices, fuel cells, actuators (devices that power physical movement), ceramics, batteries, absorbents, catalysts, storage devices, ...

What is better than carbon nanotubes? ›

Graphene is also better at transferring its properties to a material with which it is mixed than carbon nanotubes.

What is the new material for microprocessor? ›

Chemists say their new semiconductor could cut processing speeds to femtoseconds, but there's a catch. Chemists accidentally invented an unusual new material that could make the next generation of computer chips much faster. The material is a molecule made of rhenium, selenium, and chlorine, and its called Re6Se8Cl2.

Can carbon nanotubes replace silicon? ›

With their excellent electrical conductivity, carbon nanotubes have long been seen as a potential replacement for silicon in transistors. However, getting there wasn't easy, and it took decades of study to overcome the three main challenges involved; material defects, manufacturing defects, and functional issues.

Why can't silicon replace carbon? ›

But why can't it form long chain compounds like carbon? Silicon is a metalloid and cannot bond with other atoms. Silicon is larger in size than carbon, and cannot hold the shared electron pair(s) strongly. Silicon is smaller in size than carbon, and cannot hold the shared electron pair(s) strongly.

Why is silicon used instead of carbon? ›

By contrast, carbon bonding of any type breaks down at such high temperatures, making carbon-based life impossible. This heat-resistant property of silicon is the main reason that silicone compounds are often used as industrial lubricants; even hot machinery runs smoothly with silicon-based grease.

How can C nanotubes enable faster computers? ›

- Carbon nanotubes are much thinner than silicon, which means they can fit more transistors on a chip and increase the computing power and speed. - Carbon nanotubes have higher electron mobility than silicon, which means they can switch between on and off states faster and more efficiently.

Can carbon nanotubes stop bullets? ›

CNT is 5–6 times stronger than Kevlar, and it also has high ballistic resistance. It can have a constant ballistic resistance even when the bullet strikes at the same spot. Even six layers of the CNT plate is enough to withstand the projectile (Fig. 1).

What is the cost of carbon nanotubes? ›

Documents
PackingsPrice (INR)
1 gm21600.00
5 gm36090.00
25 gm81090.00
100 gm189090.00
3 more rows

Why are carbon nanotubes so expensive? ›

Yes, carbon nanotubes are expensive since they are rare, and they are like supermaterials.

What is the difference between a MOSFET and a CNTFET? ›

The advantage of using a CNTFET device in the nanometer regime is to increase the threshold voltage at 10 nm and beyond the channel length. In the case of the MOSFET while reducing the channel length, the threshold voltage is also reduced, which lead to more leakage power.

What do scientists think is the next step in using carbon nanotube transistors? ›

The next steps, already underway, will be to build different types of integrated circuits out of CNFETs in an industrial setting and explore some of the new functions that a 3D chip could offer, he says.

How does a CNFET work? ›

Like MOSFETs, CNTFETs have three terminals: source, gate and drain. When the gate is on, the current transmits from the source to the drain through a semiconducting carbon nanotube channel. The segment between the drain/source and the gate is heavily doped to provide low resistance.

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